Electron Transfer Reactions in Organic Chemistry. VIII. Synchronous Electron-proton Transfer in the Oxidation of Alkylbenzenes by 12-Molybdocerate(IV) Ion.
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چکیده
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Electron transfer versus proton transfer in gas-phase ion/ion reactions of polyprotonated peptides.
The ion/ion reactions of several dozen reagent anions with triply protonated cations of the model peptide KGAILKGAILR have been examined to evaluate predictions of a Landau-Zener-based model for the likelihood for electron transfer. Evidence for electron transfer was provided by the appearance of fragment ions unique to electron transfer or electron capture dissociation. Proton transfer and ele...
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1986
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.40b-0079